MOLPRO Basis Query, element=Cu, basis=aVDZ-PP_OPT, l=f

Basis Cu f aVDZ-PP_OPT
Primitives	Contractions...
21.890890	1.000000	0.000000	0.000000	0.000000	0.000000
8.330700	0.000000	1.000000	0.000000	0.000000	0.000000
5.569378	0.000000	0.000000	1.000000	0.000000	0.000000
1.352344	0.000000	0.000000	0.000000	1.000000	0.000000
0.397626	0.000000	0.000000	0.000000	0.000000	1.000000

Comment: J.G. Hill and K.A. Peterson, J. Chem. Theory Comput. 8, 518 (2012).