MOLPRO Basis Query, element=Cu, basis=aVQZ-PP_OPT, l=f

Basis Cu f aVQZ-PP_OPT
Primitives	Contractions...
27.811600	1.000000	0.000000	0.000000	0.000000	0.000000
18.470410	0.000000	1.000000	0.000000	0.000000	0.000000
12.327110	0.000000	0.000000	1.000000	0.000000	0.000000
4.888539	0.000000	0.000000	0.000000	1.000000	0.000000
1.624284	0.000000	0.000000	0.000000	0.000000	1.000000

Comment: J.G. Hill and K.A. Peterson, J. Chem. Theory Comput. 8, 518 (2012).