MOLPRO Basis Query, element=Cu, basis=awCVQZ-PP_OPT, l=f

Basis Cu f awCVQZ-PP_OPT
Primitives	Contractions...
32.026860	1.000000	0.000000	0.000000	0.000000
7.417418	0.000000	1.000000	0.000000	0.000000
3.175571	0.000000	0.000000	1.000000	0.000000
1.416328	0.000000	0.000000	0.000000	1.000000

Comment: J.G. Hill and K.A. Peterson, J. Chem. Theory Comput. 8, 518 (2012).