MOLPRO Basis Query, element=Cu, basis=awCVTZ-PP_OPT, l=f

Basis Cu f awCVTZ-PP_OPT
Primitives	Contractions...
24.873520	1.000000	0.000000	0.000000	0.000000
6.313110	0.000000	1.000000	0.000000	0.000000
2.327985	0.000000	0.000000	1.000000	0.000000
0.682437	0.000000	0.000000	0.000000	1.000000

Comment: J.G. Hill and K.A. Peterson, J. Chem. Theory Comput. 8, 518 (2012).