MOLPRO Basis Query, element=Cu, basis=awCVQZ-PP_OPT, l=h

Basis Cu h awCVQZ-PP_OPT
Primitives	Contractions...
19.601210	1.000000	0.000000	0.000000	0.000000
5.648684	0.000000	1.000000	0.000000	0.000000
2.382829	0.000000	0.000000	1.000000	0.000000
0.699566	0.000000	0.000000	0.000000	1.000000

Comment: J.G. Hill and K.A. Peterson, J. Chem. Theory Comput. 8, 518 (2012).