MOLPRO Basis Query, element=Cu, basis=awCVQZ-PP_OPT, l=s

Basis Cu s awCVQZ-PP_OPT
Primitives	Contractions...
15.659560	1.000000	0.000000	0.000000	0.000000
9.029141	0.000000	1.000000	0.000000	0.000000
2.126129	0.000000	0.000000	1.000000	0.000000
0.396499	0.000000	0.000000	0.000000	1.000000

Comment: J.G. Hill and K.A. Peterson, J. Chem. Theory Comput. 8, 518 (2012).