print,orbitals,civector
 geometry={Cu}
 basis={
 default,vtz
 set,avas
 default,vtz
 sp,cu,vtz;c
 d,cu,vtz
 c,1.8,  0.002646  0.020501  0.082753  0.209939  0.327763  0.345424  0.271188  0.145080 !3d
 c,1.8, -0.003764 -0.029110 -0.121384 -0.314695 -0.384907  0.076640  0.525780  0.337258 !4d
 }

 {avas,minao_basis=avas
 center,1,4s,3d,4d}   !generate AVAS starting orbitals for the subsequent CASSCF
 {df-casscf}